Why is benzyl chloride reactive

Lewis, R. Hoboken, NJ. Unstabilized benzyl chloride readily undergoes a self-condensation reaction in the presence of all common metals except nickel and lead with the liberation of heat and hydrogen chloride.

The decomposition can reach explosive violence in presence of metals such as iron. Oxidizers, acids, copper, aluminum, magnesium, iron, zinc, tin [Note: Can polymerize when in contact with all common metals except nickel and lead. Hydrolyzes in H2O to benzyl alcohol]. National Institute for Occupational Safety and Health.

The chloride is usually but not always stabilized in storage by addition of aqueous alkali or anhydrous amines as acid acceptors. A kg batch which was not stabilized polymerized violently when charged into a reactor. Your Response.

Q: Each of the solvent given should effectively separate one of the following mixtures by thin-layer chromatography. Match the appropriate solvent with the mixture that you would expect to separate well with that solvent.

The more reactive an atom, the higher its potential energy. Which atom has higher potential energy, neon or fluorine? Neon is hardly reactive at all. When it reacts, it will make news. Fluorine is a very reactive element. It is. Calculate the approximate boiling point of a mixture of bromobenzene and water at atmospheric pressure.

A table of vapor pressure of water and bromobenzene at various temperatures is given. Vapor Pressures mmHg Temperature c. Which of the following is true? Cesium is the most active group 1 metal, because its valence electron is held more tightly than the others in the same group.

Hence, 1-iodo butane is more reactive than 1-chloro butane. The SN 2 reaction is a one step reaction process. In this reaction mechanism the nucleophile attack the carbon atom from the opposite side of the leaving group.

That is ,bond making and bond breaking in SN 2 reaction occurs simultaneously. Now, vinyl chloride have a ethylenic double bond and chlorine has three lone of electrons. So, this lone pair of electron on chlorine atom participate in resonance with the pi electrons. Hence ,C — Cl bond gains partially double bond character. Therefore, the breaking of C — Cl bond is not so easy.

For the above reason, vinyl chloride is inactive in SN 2 reaction mechanism. Now, in case of chloro benzene ,the lone pair on chlorine atom under goes resonance with the pi electrons of benzene ring. So, C —Cl bond of chloro benzene gets double bond character. Hence, the breaking of C — Cl bond is not so easy. Consequently, chloro benzene is inactive in SN 2 reaction mechanism. Why benzyl chloride is highly reactive in SN 1 reaction in spite of primary halide?

How the rate of SN 1 and SN 2 reaction depends on the nature of leaving group? Which one is more active, 1-iodo butane or 1-chloro butane towards SN 2 reaction? Why vinyl chloride is inactive in SN 2 reaction? Why chloro benzene is inactive in SN 2 reaction?

What is Dow process?